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Two coordination polymers, formulated as {[Cd(1,4-BDC)(ppene)]·CH3CN}n (1) and [Cd(H2O)(1,2,4-HBTC)(ppene)0.5]n (2) have been synthesized through the solvothermal reactions between Cd(NO3)2·4H2O and 4-pyr-poly-2-ene (ppene) in the presence of 1,4-benzenedicarboxylic acid (1,4-H2BDC) or its derivative 1,2,4-benzenetricarboxylic acid (1,2,4-H3BTC). These two compounds were structurally characterized...
A carboxylic group-modified poly(acrylonitrile) fiber (CPAN) was prepared and used as a substrate for aniline adsorption and polyaniline (PANI) deposition in this study. Results from batch adsorption tests showed that grafting of carboxylic group could substantially improve the adsorption capacity of CPAN for aniline monomer at optimal pH 3.0–6.0; however, in strong acidic solutions, both the raw...
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