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Many carbonic anhydrase (CA)–mimetic catalysts have active sites composed of a Zn ion coordinated with multiple nitrogens of azacyclic compounds. In this study, some divalent transition metal ions (Co2+, Cd2+, and Ni2+) were examined as potential substitutes for the Zn cofactor when preparing CA–mimetic catalysts by means of self-assembly of histidyl bolaamphiphiles. The self-assembly of histidyl...
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