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Metal Phosphide Nanoparticles
In article number 2306621, Alexis Bordet, Walter Leitner, and co‐workers report the preparation of metal phosphide nanoparticles through the reaction of metal chloride complexes with tris(trimethylsilyl)phosphine. In the reaction, the release of the by‐product SiClMe3 acts as a driving force. The exploitation of the strength of the Si–Cl bond as compared to many metal–Cl...
Metal chloride complexes react with tris(trimethylsilyl)phosphine under mild condition to produce metal phosphide (TMP) nanoparticles (NPs), and chlorotrimethylsilane as a byproduct. The formation of Si–Cl bonds that are stronger than the starting M‐Cl bonds acts as a driving force for the reaction. The potential of this strategy is illustrated through the preparation of ruthenium phosphide NPs using...
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