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Cobalt metal–organic framework (MOF) materials CoL(1,4-chdc)·mH2O (1,4-chdc=1,4-cyclohexanedicarboxylic acid, L1=1,2-di(4-pyridyl)ethylene, and m=0 for 1Co; L2=1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene and m=2 for 2Co) were assembled in a MeOH–H2O solvent system. They crystallized in a monoclinic system with space group P2(1)/c, Z=4, a=9.479(4)Å, b=13.704(6)Å, c=14.455(6)Å, and β=99.424(6)° for 1Co,...
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