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A kind of novel nanocoating based on star polymers and graphene was developed. The hydroxyl functionalized star polymers were synthesized by Activators Regenerated by Electron Transfer Atom Transfer Radical Polymerization (ARGET ATRP) using core-first approach. The branching behavior, copolymer composition and glass transition temperature was characterized clearly. Graphene/star polymer coating shows...
The reaction kinetics and gelation behavior in atom transfer radical polymerization (ATRP), reversible addition–fragmentation chain transfer (RAFT), and conventional free radical copolymerizations (FRP) of oligo(ethylene glycol) methyl ether methacrylate (OEGMEMA) and oligo(ethylene glycol) dimethacrylates (OEGDMAs) were investigated and compared with respect to the polymerization rate, gel point,...
The development of networks and structural heterogeneity in the atom transfer radical polymerization (ATRP) of dimethacrylates was studied. The structural and kinetic evolutions during the polymerization were followed using differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and extraction/swelling measurement. The reversible activation/deactivation equilibrium between growing...
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