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An equation of state that can be used for phase equilibrium and other thermodynamic property calculations at high pressures is developed for systems that contain aqueous solutions of strong electrolytes and molecular species. The proposed equation of state is based upon contributions to the Helmholtz free energy from a non-electrolyte term and three electrolyte terms. The non-electrolyte term comes...
An implicit optimisation scheme is formulated to find the Kihara potential parameters for methane and ethane, using experimental hydrate formation data from both pure methane and ethane hydrates and hydrates formed from mixtures of methane and ethane. In this method, all three Kihara potential parameters, for both methane and ethane, are allowed to be adjustable parameters. Phase equilibria calculations,...
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