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Photoemission studies reveal the existences of metallic Rb 4 C 60 and Rb 5 C 60 surface phases on the top layer of C 60 single crystal. After Rb 3 C 60 thin film with thickness of nanometers has formed on the (111) surface layers of the C 60 single crystal, the excess deposition of Rb atoms do not induce the bulk-like...
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