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The surface modification of microcrystalline cellulose (MCC) powder with poly(isobutyl vinyl ether) (PIBVE) chains of block copolymers of MCC and PIVBE (MCC-block-PIBVE) was produced by ball milling of MCC with isobutyl vinyl ether (IBVE) in vacuum at 77K. The polymerization of IBVE was initiated by mechano-cations of MCC (MCC+) on the MCC powder surface in vacuum at 77K. MCC+s located on the surface...
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