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Hydrothermal reaction of cobalt nitrate, phenylmalonic acid, and 4,4′-dipyridylamine (dpa) resulted in formation of the coordination polymer [Co 2 (phac) 4 (dpa) 2 (H 2 O)] (1, phac=phenylacetate), where the phac ligand is formed in situ by the decarboxylation of phenylmalonic acid. Binuclear [Co 2 (phac) 4 (H 2 O)] units with both bridging and...
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