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Oxidation potentials of 1,2,3,4-dibenzocycl[2.2.3]azines 2a-d were obtained by cyclic voltammetry, which shows remarkably large effect of the substituents at the 2 position, ranging from +0.59 to +0.85 V vs NHE. In contrast to the parent cycl[2.2.3]azine 1, the radical cation species were readily generated from the 1,2,3,4-dibenzocycl[2.2.3]azines2a-c upon oxidation with AgClO 4 . The simulated...
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