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D5h‐symmetric fullerene C70 (D5h‐C70) is one of the most abundant members of the fullerene family. One longstanding mystery in the field of fullerene chemistry is whether D5h‐C70 is capable of accommodating a rare‐earth metal atom to form an endohedral metallofullerene M@D5h‐C70, which would be expected to show novel electronic properties. The molecular structure of La@C70 remains unresolved since...
So ähnlich wie Steinsalz: In Fulleren eingekapseltes Li+ (Li+@C60) entspricht durch seine Kugelform und positive Ladung einem Alkalimetallkation und kristallisiert mit PF6− in einer Steinsalz‐Struktur. C60 (grün) und PF6− (orange) sind unterhalb 370 K perfekt ausgerichtet, während sich Li+ (violett) im Käfig bewegt (siehe Bild). Unterhalb 100 K lassen sich zwei Li+‐Positionen an zwei Polen des C60...
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