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A flexible thioether ligand, 1,3-bis(methylthiomethyl)benzene (L) has been employed to prepare supramolecular assemblies with silver salts of various anions such as NO3−, BF4−, PF6− and SbF6−. X-ray structural analysis reveals that even though the same metal ion (Ag+) and ligand (L) were used to react under the same conditions, anions have played a critical role in driving the variation of metal–ligand...
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