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Chromium-based metal-organic frameworks MIL-101 and MIL-100 catalyzed oxidation of propylene glycol (PG) using tert-butyl hydroperoxide (TBHP) as oxidant. The main oxidation product was hydroxyacetone (HA) while minor oxidation products were acetaldehyde and acetic acid. The best results (88% selectivity toward HA at ca. 10% PG conversion) were achieved over MIL-101 using acetonitrile as solvent....
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