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Dense, closed, homogeneous brass/tin/germanium multilayers have been prepared by electrochemical methods. The stacks were electrodeposited on molybdenum-sputtered soda-lime glass. Brass was deposited first from an aqueous pyrophosphate electrolyte. Then, tin was deposited from a tin(II) pyrophosphate electrolyte. Germanium was deposited as the top film from 5 vol% GeCl4 in propylene glycol. The composition...
Ternary copper-zinc-tin coatings have been prepared by a one-step electrodeposition on molybdenum sputtered soda-lime glass (SLG) (20ÿ20 mm2) from an aqueous pyrophosphate electrolyte at room temperature. The plating bath contains copper(II), zinc(II), tin(II) and potassium pyrophosphate at pH=10. The influence of pyrophosphate as a complexing agent is characterized by speciation simulation, cyclic...
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