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Liquid-phase cycloisomerization of 5-(o-tolyl)-pentene (OTP) was conducted using a commercial nanocrystalline zeolite BEA. Zeolite BEA was a good catalyst for selective synthesis of 1,5-dimethyltetralin (1,5-DMT). However, over certain zeolite BEA, isomerization of 1,5-DMT to other isomers occurred after cyclization of OTP was almost complete at high temperatures. Textual properties of nanocrystalline...
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