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10H‐Dibenzo[b,e][1,4]thiaborinine 5,5‐dioxide (SO2B)—a high triplet (T1=3.05 eV) strongly electron‐accepting boracycle was successfully utilised in thermally activated delayed fluorescence (TADF) emitters PXZ‐Dipp‐SO2B and CZ‐Dipp‐SO2B. We demonstrate the near‐complete separation of highest occupied and lowest unoccupied molecular orbitals leading to a low oscillator strength of the S1→S0 CT transition,...
10H‐Dibenzo[b,e][1,4]thiaborinine 5,5‐dioxide (SO2B)—a high triplet (T1=3.05 eV) strongly electron‐accepting boracycle was successfully utilised in thermally activated delayed fluorescence (TADF) emitters PXZ‐Dipp‐SO2B and CZ‐Dipp‐SO2B. We demonstrate the near‐complete separation of highest occupied and lowest unoccupied molecular orbitals leading to a low oscillator strength of the S1→S0 CT transition,...
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