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Four copper(II) complexes (1–4) and a cobalt(II) complex (5) derived from 4-bromo-2-(hydroxymethyl)pyridine (L 1 ) or 5-bromo-2-hydroxymethyl)pyridine (L 2 ) with Cu(NO 3 ) 2 ·3H 2 O, CuCl 2 ·2H 2 O and CoCl 2 ·6H 2 O have been synthesized and their respective crystal structures studied. They show specific influences owing to...
A designed series of cyclam type macrocyclic ligands 1–3 that feature a different degree of saturation and number of functional appendages of the macroring, including preparation of the respective Cu(II) perchlorate complexes 1a–3a, was synthesized. Comparative discussion of the X-ray crystal structures of the free ligands and the corresponding complexes shows that dependent on the structure of the...
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