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A new supramolecular complex [Hg 6 Sb 4 ](InBr 6 )Br (1) has been prepared by the solid-state reaction of HgBr 2 with elemental In and Sb at 450°C. The crystal structure of 1 features a three-dimensional [Hg 6 Sb 4 ] 4+ framework with cavities of two different sizes occupied by different kinds of guest anions. The bigger cavities are filled with...
A new synthetic approach with the advantage of low cost and facile operation, which is characterized by using Hg(CN) 2 as starting material, has been successfully established for the preparation of Hg 1−X Cd x Te (MCT) materials with different x values, especially the Hg rich MCT. Three new compounds, namely Hg 0.90 Cd 0.10 Te (1), Hg 0.32 Cd 0.68...
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