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The heterogeneous and multifunctional characteristics of lignin is a paradox for its potential in polymer applications, despite its renewable and aromatic nature. We demonstrate a simple approach to the preparation of renewable lignin-grafted polymers via robust copper-free thermal click chemistry. High lignin content polymers were prepared between polymer pairs containing azide and alkyne groups...
A facile method to prepare cationic cobaltocenium‐containing polyelectrolyte is reported. Cobaltocenium monomer with methacrylate is synthesized by copper‐catalyzed azide–alkyne cycloaddition (CuAAC) reaction between 2‐azidoethyl methacrylate and ethynylcobaltocenium hexafluorophosphate. Further controlled polymerization is achieved by reversible addition–fragmentation chain transfer polymerization...
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