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The glycodecapeptide AcPAPGS(αGalNAc)T(αGalNAc)APPA and the C-terminal glycohexapeptide AcS(αGalNAc)T(αGalNAc)APPA have been synthesized by applying the N-terminal Fmoc group in combination with the heptyl ester cleavable by lipase-catalyzed hydrolysis at pH 7. The solution conformation of these MUC1-related synthetic glycopeptides and the control, non-glycosylated decapeptide AcPAPGSTAPPA have been...
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