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As the chemistry of saccharides and related molecular species plays a significant role in the metabolic pathways of living organisms, detecting the presence and concentration of biologically important sugars in aqueous solution is necessary in a variety of medicinal and industrial contexts. The recognition of d-glucose is of particular interest, for example in the monitoring of diabetics. Recent research...
The first example of a positive, homotropic system in aqueous saccharide-binding has been achieved using a Ce(IV) bis(porphyrinate) double decker scaffold bearing two pairs of boronic acid groups (compound 2). In this system, the binding of the first guest (1:2 saccharide/boronic acid complex) suppresses the rotational freedom of the two porphyrin planes, which facilitates the binding of the second...
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