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The lithium–sulfur (Li–S) battery is considered as one of the most promising options because the redox couple has almost the highest theoretical specific energy (2600 Wh kg−1) among all solid anode‐cathode candidates for rechargeable batteries. The “solid–liquid–solid” mechanism has become a dominating phase transformation process since it was first reported, although this cathode mode suffers from...
Lithium sulfide (Li2S) is a promising cathode material with high capacity, which can be paired with nonlithium metal anodes such as silicon or tin so that the safety issues caused by the Li anode can be effectively avoided. However, the Li2S full cell suffers from rapid capacity degradation due to the dissolution of intermediate polysulfides. Herein, a Li2S/Si full cell is designed with a Li2S cathode...
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