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Artificial Enzymes
In article number 2108646, Lang Ma, Chong Cheng, Li Qiu, and co‐workers report a new vanadium‐based artificial enzyme (VOx‐AE) for efficient reactive oxygen species (ROS)‐catalysis by modulating the d electrons in the active centers via a unique Zn–O–V bridge structure. The VOx‐AE exhibits enhanced ROS catalytic activity, augmented eradication of drug‐resistant bacteria, and comparable...
Nanomaterials‐based artificial enzymes (AEs) have flourished for more than a decade. However, it is still challenging to further enhance their biocatalytic performances due to the limited strategies to tune the electronic structures of active centers. Here, a new path is reported for the de novo design of the d electrons of active centers by modulating the electron transfer in vanadium‐based AEs (VO...
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