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The heterogeneous and multifunctional characteristics of lignin is a paradox for its potential in polymer applications, despite its renewable and aromatic nature. We demonstrate a simple approach to the preparation of renewable lignin-grafted polymers via robust copper-free thermal click chemistry. High lignin content polymers were prepared between polymer pairs containing azide and alkyne groups...
Composite latex particles with a polydimethylsiloxane PDMS core and a poly(methyl methacrylate-co-n-butyl acrylate) P(MMA-BA) copolymer shell were synthesized by seeded emulsion polymerization using the PDMS latex as the seed. The compatibility between the two polymer phases was changed by introducing vinyl groups in the latex core. Monomer conversions and particle size evolution were monitored to...
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