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The structure of anionic motif, oxidation state and coordination of iron in the series of glasses (mol.%): 40 Na2O, (20-x) Al2O3, x Fe2O3, 40 P2O5 considered as matrices for immobilization of high Fe/Al legacy high level waste were determined by FTIR, Raman and Mössbauer study. The glass network is built from ortho- and pyrophosphate units linked by aluminum-oxygen and iron-oxygen polyhedra. Iron...
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