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We have previously shown that the incorporation of an 8‐atom all‐hydrocarbon ‘staple’ at positions i and i +3 of a synthetic peptide results in substantial stabilization of the α‐helical conformation. As part of our ongoing effort to explore the scope and utility of all‐hydrocarbon stapling systems, we have investigated and report herein the properties of a new i, i +3 stapling system that employs...
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