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Photodegradation of pivalic acid [(CH3)3CCOOH] on a Pt/TiO2 photocatalyst was studied by time-resolved IR spectroscopy in the microsecond-to-millisecond time region. A vibrational band due to t-butyl radical species, as a reaction intermediate, was observed at 1456cm−1 along with decrease of reactant, bridge-adsorbed pivalate, and product formation. The product did not have vibrational bands in the...
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