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Nitric oxide adsorption, thermal desorption and decomposition on a Rh model catalyst was studied using Pulsed Field Desorption Mass Spectrometry (PFDMS). This relaxation-type technique was applied as a chemical probe allowing the composition analysis in selected areas of about 200 atomic surface sites of the catalyst (with the latter being given in a nearly hemispherical morphology of a small tip)...
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