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A thermally durable all-solid-state lithium ion battery composed of a complex hydride, oxide electrolytes, and LiNi1/3Mn1/3Co1/3O2 active material is developed. This battery exhibits a discharge capacity of 56 mAh g−1, and the tenth capacity retention ratio is 29% at 150 °C owing to the large contact resistance between the electrolyte layer and the composite positive electrode layer. This large contact...
A composite negative electrode for use in bulk-type all-solid-state batteries was developed by combining the solid electrolyte Li4(BH4)3I (LiBH4 doped with LiI), acetylene black (AB) (as a conductive additive), and lithium titanate (Li4Ti5O12, LTO). Because of the highly deformable nature of the complex hydride, hand milling and subsequent uniaxial pressing were sufficient to ensure tight interfacial...
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