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Interpenetration in metal–organic frameworks (MOFs) is an intriguing phenomenon with significant impacts on their properties, and functional applications. Herein, we show that a 7‐fold interpenetrated MOF (1) is transformed into an 8‐fold interpenetrated MOF by the loss of DMF in a single‐crystal‐to‐single‐crystal manner. This is accompanied by a giant enhancement of the second harmonic generation...
„Ein Baby‐Gepard kann weiter springen als seine Mutter” lautet ein altes Sprichwort in Tamil. In diesem Fall zeigt ein achtfach interpenetriertes MOF eine enorme Verstärkung in der Frequenzverdopplung im Vergleich zum siebenfach interpenetrierten Vorläufer‐MOF. Wie R. E. Dinnebier, Q.‐H. Xu, J. J. Vittal et al. in ihrem Forschungsartikel auf S. 843 zeigen, resultiert das achtfach interpenetrierte...
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