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Oxidative addition of donor‐functionalised 4‐iodoimidazolium salts to palladium(0) provides a selective route for the preparation of abnormal chelating N‐heterocyclic carbene complexes and enables the introduction of a variety of donor groups. The activation of the C4 position does not necessitate protection of the imidazolium C2 position, thereby leaving this site available for further modification...
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