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Zwei schalenförmige Moleküle mit komplementärem elektronischem Charakter, ein Truxen‐Derivat als Donor und ein Hemifulleren als Akzeptor, bilden in Lösung heteromolekulare Dimere mit Bindungskonstanten im Bereich von 103 M‐1, wie E. Ortí, D. M. Guldi, L. T. Scott, N. Martín et al. in der Zuschrift auf S. 2202 ff. beschreiben. Damit wurde erstmals beobachtet, dass ein Fullerenfragment das Verhalten...
Herein, we investigate the association of a fullerene fragment, hemifullerene C30H12, with an electron‐donating bowl‐shaped tetrathiafulvalene derivative (truxTTF). UV/Vis titrations and DFT calculations support formation of the supramolecular complex, for which an association constant of log Ka=3.6±0.3 in CHCl3 at room temperature is calculated. Remarkably, electron transfer from truxTTF to C30H12...
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