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Self‐assembly of a trigonal building subunit with diaminotriazines (DAT) functional groups leads to a unique rod‐packing 3D microporous hydrogen‐bonded organic framework (HOF‐3). This material shows permanent porosity and demonstrates highly selective separation of C2H2/CO2 at ambient temperature and pressure.
Besser als verlangt: Die Volumenspeicherkapazität für Methan von UTSA‐20 (siehe Bild) ist mit 195 cm3 cm−3 höher als der von der US‐Energiebehörde bei Raumtemperatur und 35 bar vorgegebene Wert von 180 cm3 cm−3. UTSA‐20, ein auf einem neuartigen trinodalen (3,3,4)‐Netz basierendes Metall‐organisches Gerüst ist dank offener Kupferpositionen und optimaler Porenräume das Material mit der höchsten Methanspeicherdichte...
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