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Covalent Organic Frameworks (COFs), an emerging class of crystalline porous materials, are proposed as a new type of support for grafting lanthanide ions (Ln3+) and employing these hybrid materials as ratiometric luminescent thermometers. A TpBpy‐COF—prepared from 1,3,5‐triformylphloroglucinol (Tp) and 2,2′‐bipyridine‐5,5′‐diamine (Bpy) grafted with Eu/Tb and Dy acetylacetone (acac) complexes can...
Kovalente organische Gerüste (COFs) können mit Eu3+‐ und Tb3+‐Komplexen gepfropft werden, welche die Porengröße des Materials verringern, wenn sie an das COF angebracht werden. Wie A. M. Kaczmarek, L. D. Carlos et al. in ihrem Forschungsartikel auf S. 1948 beschreiben, emittieren die Eu3+‐ und Tb3+‐Ionen rotes bzw. grünes Licht und erlauben eine Nutzung des Systems als neuartiges Lumineszenz‐Thermometer...
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