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Resonance Raman spectra of heteroatom substituted ruthenium(II)-allenylidene complexes, obtained by irradiation into the second electronic absorption band, clearly prove the d(Ru)->π*(CCC) MLCT character of the corresponding electronic transition. The complexes are not significantly luminescent at room temperature, but in solvent glasses at 77 K, emission is observed. Only some of the complexes...
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