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The synthesis and characterization of a covalent all‐fullerene C60‐Lu3N@Ih‐C80 electron donor–acceptor conjugate has been realized by sequential 1,3‐dipolar cycloaddition reactions of azomethine ylides on Lu3N@Ih‐C80 and C60. To the best of our knowledge, this is the first time that two fullerenes behaving as both electron donor (Lu3N@Ih‐C80) and acceptor (C60) are forming an electroactive dumbbell...
Ein Donor‐Akzeptor‐Konjugat das nur aus Fullerenen besteht, wurde entwickelt, synthetisiert und charakterisiert. In ihrer Zuschrift auf S. 7006 ff. beschreiben M. Solà, D. M. Guldi, N. Martín et al. die C60‐Lu3N@Ih‐C80‐Hantel und demonstrieren, dass photoinduzierter Elektronentransfer zur Bildung eines langlebigen ladungsgetrennten Triplettzustands führt.
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