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A comparison between the stereo-outcome of the carbopalladation-functionalization of monosubstituted allenes and the palladium-catalyzed substitution of dienic acetates 1 and 4 by a malonate anion shows that the same π-allyl intermediate should be involved in both processes. During this study, an influence of the counterion of the palladium complex on the stereoselectivity of the process was clearly...
Cross-conjugated dienols 3 were satisfactorily obtained via the palladium-catalyzed coupling reaction of 2-iodo-2-alken-1-ol 6 with vinyl Grignard reagents.
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