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A novel artificial receptor 1 containing the indolocarbazole-NH moieties as the recognition sites exhibited high selectivity and sensitivity toward F− over other typical anionic species in DMSO solution. Upon addition of F− into the solution, receptor 1 showed a remarkable ratiometric shift of the fluorescence maximum from 535 to 590nm, and also a prominent color change from light yellow to orange,...
By retaining the quadrapyridyl receptor of polypyridylhexaazatriphenylene (a Cd 2+ sensor reported by us) and extending its chromophoric group with pyrene, a chemical sensor (1) was designed and synthesized in this work. This sensor exhibit selective off-on fluorescence response to Cd 2+ over other metal ions, and the detection limit is as low as 0.02μM. The Cd 2+ sensing of...
Two hexaazatriphenylene (HAT) derivatives, 2,3,6,7-tetramethyl-10,11-di(pyridin-2-yl)dipyrazino[2,3-f:2',3'-h]quinoxaline (1) and 2,3-dimethyl-6,7,10,11-tetra(pyridin-2-yl)dipyrazino[2,3-f:2',3'-h]quinoxaline (2), were designed and synthesized. Both 1 and 2 exhibited high off–on fluorescent selectivity for Cd 2+ over many other metal ions, and the detection limits were determined to be 0.6...
Two C 2 -symmetrical hexaazatriphenylene (HAT) derivatives, 2,3-diphenyl-6,7,10,11-tetra(pyridin-2-yl)dipyrazino[2,3-f:2′,3′-h]quinoxaline (1) and 2,3,6,7-tetraphenyl-10,11-di(pyridin-2-yl)dipyrazino[2,3-f:2′,3′-h]quinoxaline (2), were designed and synthesized by the condensation reaction of 1,2-diamines and 1,2-diketones. Both compounds 1 and 2 exhibit sensitive, ratiometric and colorimetric...
A new ditopic ion pair receptor 1 containing two biindole moieties and a bis-benzocrown ether unit shows a remarkable color switching (ON- and -OFF) function induced by anion (F − ) and cation (K + ) recognition. The ditopic receptor 1 binds in a cooperative fashion to HSO 4− in the presence of 1·K + and acts as a selective ditopic receptor to recognize ion pairs...
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