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The synthesis of the selenium‐based ligand L1SeSeL1 (2,2’‐diselanediylbis(N,N‐bis(pyridin‐2‐ylmethyl)ethan‐1‐amine) is described along with its reactivity with cobalt(II) salts. The cobalt(II)‐diselenide complex [Co2(L1SeSeL1)Cl4] was obtained in good yield, and its spectroscopic properties closely resemble that of its sulfur analog. Reaction of L1SeSeL1 with Co(II) thiocyanate results in the formation...
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