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Valence d-orbital energies of the first row transition metals are close to the frontier π-orbital energies of o-benzoquinones. Complexes prepared with quinone ligands most commonly have the quinone coordinated with the metal in the form of a semiquinonate (SQ) radical-anion or as a catecholate (Cat) dianion. In a few unique complexes it has been possible to observe intramolecular electron transfer...
Valence d-orbital energies of the first row transition metals are close to the frontier π-orbital energies of o-benzoquinones. Complexes prepared with quinone ligands most commonly have the quinone coordinated with the metal in the form of a semiquinonate (SQ) radical-anion or as a catecholate (Cat) dianion. In a few unique complexes it has been possible to observe intramolecular electron transfer...
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