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The preparation of the polymeric chain complex, {[Mn(bic)(H 2 O)] 2 2Br 2H 2 O)} n (2) is reported. Characterization is made by single X-ray structure, IR and magnetochemistry data. Each seven-coordinate manganese ion has a slightly distorted pentagonal bipyramidal coordination geometry. Bicine is a hexadentate ligand using one nitrogen, three oxygen and one μ...
The synthesis, X-ray structure and magnetochemical properties of the one-dimensional polymeric bicinate (bic - ) manganese complex {[Mn(bic)Cl] 2 2(H 2 O)} n are reported. Each manganese ion has distorted octahedral coordination geometry. Bicine is a pentadentate ligand using one nitrogen, and four oxygen atoms to coordinate to the Mn II ion. The two...
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