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This chapter focuses on the kinetics of spin-state relaxation, primarily in iron(II) complexes in solution. Initial work carried out during the 1970s and early 1980s by chemical relaxation methods is briefly reviewed, followed by a more detailed account of the laser photoperturbation technique and the photophysics which underpin this approach, now widely adopted as the method of choice for spin crossover...
This chapter focuses on the kinetics of spin-state relaxation, primarily in iron(II) complexes in solution. Initial work carried out during the 1970s and early 1980s by chemical relaxation methods is briefly reviewed, followed by a more detailed account of the laser photoperturbation technique and the photophysics which underpin this approach, now widely adopted as the method of choice for spin crossover...
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