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Three pyridinylimine palladium(II) complexes of the type [(C 5 H 4 N)HC N (CH 2 )n-CH 3 ] PdCl 2 (n=4, 7, 11) were synthesized by reacting (COD)PdCl 2 with the appropriate pyridyl-imine ligand. The crystal structure of the complex, where n=7 was determined using single crystal X-ray crystallography and this displays a striking co-planar geometry, with...
The new pyridylimine complex, {N-dodecyl-N-[(1E)-pyridin-2-ylmethylene]amine}dichloro palladium was synthesized by the reaction of N-(dodecanyl)pyridyl-2-methanimine with (COD)PdCl 2 . The complex when activated with methylaluminoxane polymerizes ethylene to produce only high-density polyethylene under mild reaction conditions.
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