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We present a new method for synthesizing cold‐resistant laminated anti‐fire glass using a K2O·nSiO2‐based ultrathin flexible membrane, which is prepared by vacuum surface treatment method with ball‐milled core–shell SiO2 emulsion (55 wt%). We systemically characterize the mechanical, optical, rheological, cold‐resistant, fire‐resistant, and weather‐resistant performances of this glass. The formation...