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Distickstoff‐Fixierungen wurden in bisherigen Studien meist mit starken Reduktionsmitteln durchgeführt. H. Masuda et al. präsentieren nun in ihrer Zuschrift auf S. 11401 eine Methode zur N2‐Aktivierung, bei der Distickstoff durch Ein‐Elektronen‐Oxidation von [Mo(depe)2(N2)2] mit einem milden Oxidationsmittel unter Bildung einer Mo≡N‐Spezies gespalten wird.
Reported here is the N2 cleavage of a one‐electron oxidation reaction using trans‐[Mo(depe)2(N2)2] (1) (depe=Et2PCH2CH2PEt2), which is a classical molybdenum(0)‐dinitrogen complex supported by two bidentate phosphine ligands. The molybdenum(IV) terminal nitride complex [Mo(depe)2N][BArf4] (2) (BArf4=B(3,5‐(CF3)2C6H3)4) is synthesized by the one‐electron oxidation of 1 upon addition of a mild oxidant,...
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