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Two new uranyl compounds [NH4][(UO2)(ipa)1.5]·H2O 1 and [(UO2)2(μ2OH)(μ3OH)(ipa)(H2O)]·H2O 2 (H2ipa = isophthalic acid) have been synthesized under hydrothermal conditions and characterized by infrared spectra (IR), thermogravimetric analysis (TGA), elemental analyses and X-ray diffraction (XRD). Structural analysis reveals compound 1 exhibits two-dimensional (2D) framework through the bridging of...
Three transition-metal-based coordination polymers (1: Co2+; 2: Ni2+ and 3: Cd2+) have been solvothermally synthesized from a newly designed polytopic ligand of 4-(carboxymethoxy)-[1,1′-biphenyl]-3,4′-dicarboxylic acid (H3Lws) that integrates both flexible aliphatic and rigid aromatic carboxylate groups. In 1, each H3Lws ligand connects two Co2+ ions in the partially deprotonated form of HLws2−, whereas...
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