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Zinc phosphide (Zn3P2) is a promising and earth-abundant alternative to traditional materials (e.g. CdTe, CIGS, a-Si) for thin film photovoltaics. The record solar energy conversion efficiency for Zn3P2 cells of 6% (M. Bhushan et al., Appl. Phys. Lett., 1980) used a Mg/Zn3P2 device geometry that required annealing to reach peak performance. Here we report photovoltaic device results and junction composition...
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