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A facile and novel way was reported here for the synthesis of hydrophobic Ag nanoparticles (NPs), using AgNO 3 , tri-n-octylphosphine (TOP) and sulfur (S) powder in process. TOP was used as solvent, reducing agent and stabilizer. S could chelate with excessive TOP to form trioctylphosphine sulfide (TOPS), which served as second capping agent. The hydrophobic Ag NPs could be transformed into...
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