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Assemblies of 5-amino-2,4,6-triiodoisophthalic acid (H 2 ATIBDC) with Cd(II) and Zn(II) in the presence of N-donor auxiliary ligand, 1,4-bis(1,2,4-triazol-1-yl)butane (btb), at ambient conditions yield two new supramolecular complexes, [Cd(ATIBDC)(btb)(H 2 O) 2 ]·3H 2 O (1), and [Zn(ATIBDC)(btb)]·2H 2 O (2). Generally, these two complexes display 1D ATIBDC ...
A novel metal–organic framework containing one-dimensional channels of formula [Zn 3 (Aco) 2 (H 2 O) 6 ] n (H 3 Aco=aconitic acid) has been synthesized and characterized by FT-IR spectroscopy, thermogravimetric analysis (TG), X-ray analysis, and solid state photoluminescence spectra. X-ray crystallographic studies reveal that there are two kinds of crystallographically...
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