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The rational design of hemocompatible materials requires a mechanistic understanding of activation processes induced at the blood–material interface. Binary self-assembled monolayers of alkyl thiols (SAMs) with various ratios of –CH 3 and –COOH terminations were used to study the relevance of hydrophobic and negatively charged surfaces for the initiation of blood coagulation. Platelet adhesion...
Self-assembled monolayers (SAMs) of alkanethiols with various terminating groups (–OH, –CH 3 , –COOH) and binary mixtures of these alkanethiols were studied with respect to their hemocompatibility in vitro by means of freshly taken human whole blood. The set of smooth monomolecular films with graded surface characteristics was applied to scrutinize hypotheses on the impact of surface chemical–physical...
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